面向高速列车裙板的仿水稻叶超疏水涂层的制备及润湿性能研究

Preparation of Biomimetic Rice-Leaf-inspired Superhydrophobic Coating and Its Wettability Performance for High-Speed Train Skirt Panels

  • 摘要:
    目的 针对高速列车裙板在雨雪、泥水和粉尘等复杂环境下易挂污、难清洗的问题,有必要在金属基体表面构筑仿水稻叶超疏水结构,以实现高速列车裙板表面功能化。
    方法 选用6005A铝合金作为基体,采用TruMicro 5250绿光飞秒激光加工系统在其表面刻写仿水稻叶条纹状沟槽多级复合微结构。试样经预处理后,在预设区域内按既定扫描路径加工一维纵向沟槽;利用SEM(扫描电子显微镜)和LSCM(激光扫描共聚焦显微镜)对表面形貌及三维粗糙度进行表征,并通过CA(接触角)与SA(滚动角)测试评估涂层的表面润湿性能。基于Cassie-Baxter模型计算表面的有效固相面积分数,分析了条纹状沟槽多级粗糙结构对润湿性的放大机理。
    结果及结论 激光处理后表面形成周期长度约90~100 μm的条纹状沟槽阵列,沟槽与脊峰表面覆盖大量微米级凸起和纳米级凸起,Sa(三维面粗糙度)约为(5.18±0.67)μm,且粗糙度在平行、垂直于沟槽方向上具有明显各向异性。6005A铝合金表面经飞秒激光诱导并自然老化后,水的CA由106.90°±1.80°提高至174.00°±0.86°,SA由黏附状态(翻转180°仍不滴落)降至5.80°±0.90°,表现出极端超疏水和低黏附特性。模拟计算表明,结构表面的有效固相面积分数约为0.8%,液滴底部超过99%的区域由稳固的空气垫支撑。研究结果表明,针对高速列车裙板等外露金属构件表面的防水、防污与自清洁功能化,飞秒激光仿水稻叶超疏水结构具有良好的应用前景。

     

    Abstract:
    Objective High-speed train skirt panels are prone to contamination and difficult to clean under complex environments such as rain and snow, muddy water, and dust. In response to these problems, it is necessary to construct a biomimetic rice-leaf-inspired superhydrophobic structure on the metal substrate surface to achieve the surface functionalization of high-speed train skirt panels.
    Method 6005A aluminum alloy is selected as the substrate, and the rice-leave-inspired strip-shaped groove multilevel composite microstructures is inscribed on its surface using TruMicro 5250 green femtosecond laser processing system. After pretreatment, one-dimensional longitudinal grooves are processed in the preset area according to a predetermined scanning path. SEM (scanning electron microscopy) and LSCM (laser scanning confocal microscopy) are used to characterize the surface morphology and three-dimensional roughness. The surface wettability performance of the coating is evaluated through CA (contact angle) and SA (sliding angle) tests. Based on the Cassie-Baxter model, the effective solid fraction of the surface is calculated, and the amplification mechanism of wettability caused by the stripe-shaped groove multilevel rough structure is analyzed.
    Result & Conclusion  After laser treatment, a stripe-shaped groove array with a periodic length of approximately 90–100 μm is formed on the above substrate surface, and the surfaces of the grooves and ridges are covered with a large number of micro-scale protrusions and nanoscale protrusions. The Sa (three-dimensional surface roughness) is approximately 5.18 ± 0.67 μm, and the roughness exhibits obvious anisotropy in the directions parallel and perpendicular to the grooves. After femtosecond laser induction and natural aging of the 6005A aluminum alloy structure, the water CA increased from 106.90 ± 1.80° to 174.00 ± 0.86°, and the SA decreases from an adhesive state (no droplet falling even when inverted by 180°) to 5.80° ± 0.90°, exhibiting extremely superhydrophobic and low adhesion characteristics. Simulation calculations show that the effective solid fraction of the structured surface is approximately 0.8%, and more than 99% of the area at the bottom of the droplet is supported by a stable air cushion. Research results indicate that the femtosecond-laser-fabricated biomimetic rice-leaf-inspired superhydrophobic structure has good application prospects for waterproofing, anti-fouling, and self-cleaning functionalization of the exposed metal component surfaces such as high-speed train skirt panels.

     

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